The influence of crucible material on the DSC thermal analysis compared to freeze-drying microscopy results
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
19/10/2012
19/10/2012
2009
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| Resumo |
The aim of this study was to investigate the influence of different crucible materials on the thermal analysis of binary systems. The thermal properties of two distinct solutions were measured both by Differential Scanning Calorimetry (DSC) and freeze-drying microscopy and the results were compared. The glass transition of the maximally freeze-concentrate (T (g)`) and the eutectic melting temperature (T (eut)) were not influenced by the crucible material. However the heat of fusion (Delta H) involved during the T (eut) as well as the Delta C (p) involved during the T (g)` of the solutions were affected. FAPESP (The State of Sao Paulo Research Foundation) CNPq (National Council for Scientific and Technological Development) |
| Identificador |
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v.98, n.1, p.203-206, 2009 1388-6150 http://producao.usp.br/handle/BDPI/19777 10.1007/s10973-009-0317-8 |
| Idioma(s) |
eng |
| Publicador |
SPRINGER |
| Relação |
Journal of Thermal Analysis and Calorimetry |
| Direitos |
restrictedAccess Copyright SPRINGER |
| Palavras-Chave | #Lyophilization #Eutectic temperature #Glass transition temperature #Differential scanning calorimetry #Freeze-drying microscopy #GLASS-TRANSITION #RELAXATION #TREHALOSE #COLLAPSE #Chemistry, Analytical #Chemistry, Physical |
| Tipo |
article original article publishedVersion |
