Carbohydrates in asymmetric synthesis: enantioselective allylation of aldehydes
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
19/10/2012
19/10/2012
2008
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| Resumo |
An enantioselective metal-mediated addition of allylic bromides to carbonyl compounds was achieved in the presence of the inexpensive and easily accessible carbohydrates saccharose and beta-cyclodextrin. The desired products were obtained in moderate to excellent yields and with up to 93% enantiomeric excess. (C) 2008 Elsevier Ltd. All rights reserved. |
| Identificador |
TETRAHEDRON LETTERS, v.49, n.33, p.4956-4957, 2008 0040-4039 http://producao.usp.br/handle/BDPI/19713 10.1016/j.tetlet.2008.05.109 |
| Idioma(s) |
eng |
| Publicador |
PERGAMON-ELSEVIER SCIENCE LTD |
| Relação |
Tetrahedron Letters |
| Direitos |
closedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
| Palavras-Chave | #CATALYSIS #LIGANDS #KETONES #COMPLEX #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
