Synthesis of benzophenones from geminal biaryl ethenes using m-chloroperbenzoic acid
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
19/10/2012
19/10/2012
2009
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| Resumo |
The oxidation of geminal biaryl ethenes 3 and 1,3-enynes 5 using m-chloroperbenzoic acid in dichloromethane at room temperature presents a catalyst-free approach for the synthesis of functionalized benzophenones 4 and ynones 6, respectively. (C) 2009 Elsevier Ltd. All rights reserved. FAPESP[07/59404-2] FAPESP[07/514669] CNPq[300613/2007-5] |
| Identificador |
TETRAHEDRON LETTERS, v.50, n.20, p.2312-2316, 2009 0040-4039 http://producao.usp.br/handle/BDPI/19694 10.1016/j.tetlet.2009.02.164 |
| Idioma(s) |
eng |
| Publicador |
PERGAMON-ELSEVIER SCIENCE LTD |
| Relação |
Tetrahedron Letters |
| Direitos |
closedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
| Palavras-Chave | #CROSS-COUPLING REACTION #ELECTROSPRAY-IONIZATION MASS #ACYL CHLORIDES #ARYLBORONIC ACIDS #SELECTIVE OXIDATION #GARCINIA-MULTIFLORA #NATURAL-PRODUCTS #DOUBLE-BOND #ALCOHOLS #MECHANISM #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
