Consecutive biocatalysis-palladium catalysis II: Synthesis of conduritol-alkyne conjugates
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
19/10/2012
19/10/2012
2009
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| Resumo |
The palladium-catalyzed cross-coupling reaction of potassium alkynyltrifluoroborates with a chemoenzymatically derived deoxyconduritol is described. Six new compounds were synthesized in moderate to good yields. The alkynyl cross-coupling reaction can be effected using 10 mol% of Pd(PPh(3))(4) as Catalyst in toluene-H(2)O in the presence Of Cs(2)CO(3) as the inorganic base. (C) 2009 Elsevier B.V. All rights reserved. CNPq FAPESP |
| Identificador |
CATALYSIS COMMUNICATIONS, v.10, n.13, p.1647-1650, 2009 1566-7367 http://producao.usp.br/handle/BDPI/19689 10.1016/j.catcom.2009.05.001 |
| Idioma(s) |
eng |
| Publicador |
ELSEVIER SCIENCE BV |
| Relação |
Catalysis Communications |
| Direitos |
closedAccess Copyright ELSEVIER SCIENCE BV |
| Palavras-Chave | #Biocatalysis #Potassium alkynyltrifluoroborates #Cyclitol conjugates #CROSS-COUPLING REACTIONS #DERIVATIVES #CHEMISTRY #HALIDES #Chemistry, Physical |
| Tipo |
article original article publishedVersion |
