2-Benzoylpyridine semicarbazone


Autoria(s): LIMA, Daniel F. de; PEREZ-REBOLLEDO, Anayive; ELLENA, Javier; BERALDO, Heloisa
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

19/04/2012

19/04/2012

2008

Resumo

The title compound, C13H12N4O, crystallizes with two independent molecules in the asymmetric unit. The compound crystallizes as the ZE isomer, where Z and E refer to the configuration around the C=N and N-C bonds, respectively, with an N-H center dot center dot center dot N-py (py is pyridine) intramolecular hydrogen bond. The dihedral angles between the least-squares planes through the semicarbazone group and the pyridyl ring are 22.70 (9) and 27.26 (9)degrees for the two molecules. There are intermolecular N-H center dot center dot center dot O hydrogen bonds.

Identificador

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, v.64, p.O177-U4093, 2008

1600-5368

http://producao.usp.br/handle/BDPI/16521

10.1107/S1600536807064628

http://dx.doi.org/10.1107/S1600536807064628

Idioma(s)

eng

Publicador

BLACKWELL PUBLISHING

Relação

Acta Crystallographica Section E-structure Reports Online

Direitos

closedAccess

Copyright BLACKWELL PUBLISHING

Palavras-Chave #BENZALDEHYDE SEMICARBAZONE #BETA-CYCLODEXTRIN #METAL-COMPLEXES #Crystallography
Tipo

article

original article

publishedVersion