cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbonyl]thioureato-kappa 2 O,S}nickel(II)


Autoria(s): PEREZ, Hiram; SILVA, Cecilia C. P. da; PLUTIN, Ana M.; SIMONE, Carlos A. de; ELLENA, Javier
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

19/04/2012

19/04/2012

2011

Resumo

In the title compound, [Ni(C(20)H(17)N(2)O(2)S)(2)], the NiII atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-[(furan-2-yl)carbonyl]thioureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Ni-S and Ni-O bond lengths lie within the range of those found in related structures. The dihedral angle between the planes of the two chelating rings is 20.33 (6)degrees.

ICTP/CLAF

Identificador

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, v.67, p.M504-U1055, 2011

1600-5368

http://producao.usp.br/handle/BDPI/16502

10.1107/S1600536811010749

http://dx.doi.org/10.1107/S1600536811010749

Idioma(s)

eng

Publicador

WILEY-BLACKWELL

Relação

Acta Crystallographica Section E-structure Reports Online

Direitos

closedAccess

Copyright WILEY-BLACKWELL

Palavras-Chave #DERIVATIVES #COMPLEXES #CU(II) #NI(II) #Crystallography
Tipo

article

original article

publishedVersion