Reações de oxidação de derivados de cis-octalinas promovidas por trinitrato de tálio (TTN)
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
26/03/2012
26/03/2012
2008
|
| Resumo |
The reaction of ten cis-octalins and cis-octalones with thallium trinitrate (TTN) leads to different products, depending mainly on the substitution pattern of the substrate. Functionalized cis-hydrindanes were obtained from the reaction of 1,2,3,4,4a,5,8,8a-octahydro-4a-methylnaphthalene and of 1,2,3,4,4a,5,8,8a-octahydro-4a,7-dimethylnaphthalene with TTN in acetonitrile, whereas a cyclic ether was formed treating 1,2,3,4,4a,5,8,8a-octahydro-6,8a-dimethylnaphthalen-1-ol with TTN in trimethylorthoformate (TMOF). FAPESP CNPq Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) |
| Identificador |
Química Nova, v.31, n.4, p.781-787, 2008 0100-4042 http://producao.usp.br/handle/BDPI/12319 10.1590/S0100-40422008000400014 http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000400014 |
| Idioma(s) |
por |
| Publicador |
Sociedade Brasileira de Química |
| Relação |
Química Nova |
| Direitos |
openAccess Copyright Sociedade Brasileira de Química |
| Palavras-Chave | #Thallium trinitrate #Cis-hydrindanes #Octalin |
| Tipo |
article original article publishedVersion |
