Avaliação por SAXS e DSC das interações entre H2O e Renex-100


Autoria(s): Campos, Daniella Dias Palombino de; Cassu, Silvana Navarro; Garcia, Renata Batista Rivero; Queiroz, Hiure Anderson Alves da Silva; Gonçalves, Rene Francisco Boschi; Kawachi, Elizabete Yoshie
Contribuinte(s)

Universidade Estadual de Campinas

Data(s)

01/01/2012

03/12/2015

03/12/2015

Resumo

The aggregation behavior of the non-ionic surfactant Renex-100 in aqueous solutions and mesophases was evaluated by SAXS in a wide range of concentrations, between 20 and 30 °C. Complementary, water interactions were defined by DSC curves around 0°C. SAXS showed that the system undergoes the following phase transitions, from diluted to concentrated aqueous solutions: 1) isotropic solution of Renex aggregates; 2) hexagonal mesophase; 3) lamellar mesophase; and 4) isotropic solution. DSC analysis indicated the presence of interfacial water above 70wt%, which agreed with the segregation of free water to form the structural mesophases observed by SAXS bellow this concentration.

355

359

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Identificador

Química Nova. Sociedade Brasileira de Química, v. 35, n. 2, p. 355-359, 2012.

0100-4042

S0100-40422012000200023

10.1590/S0100-40422012000200023

http://dx.doi.org/10.1590/S0100-40422012000200023

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000200023

http://www.repositorio.unicamp.br/jspui/handle/REPOSIP/23919

http://repositorio.unicamp.br/jspui/handle/REPOSIP/202519

Idioma(s)

pt

Publicador

Sociedade Brasileira de Química

Relação

Química Nova

Direitos

aberto

Fonte

SciELO

Palavras-Chave #interfacial water #non-ionic surfactant #mesophase
Tipo

Artigo de periódico