The Total Synthesis Of (-)-cryptocaryol A.
| Contribuinte(s) |
UNIVERSIDADE DE ESTADUAL DE CAMPINAS |
|---|---|
| Data(s) |
01/03/2015
27/11/2015
27/11/2015
|
| Resumo |
A stereoselective total synthesis of (-)-cryptocaryol A () is described. Key features of the 17-step route include the use of three boron-mediated aldol reaction-reduction sequences to control all stereocenters and an Ando modification of the Horner-Wadsworth-Emmons olefination that permitted the installation of the Z double bond of the α-pyrone ring. 13 3575-84 |
| Identificador |
Organic & Biomolecular Chemistry. v. 13, n. 12, p. 3575-84, 2015-Mar. 1477-0539 10.1039/c5ob00080g http://www.ncbi.nlm.nih.gov/pubmed/25695350 http://repositorio.unicamp.br/jspui/handle/REPOSIP/202133 25695350 |
| Idioma(s) |
eng |
| Relação |
Organic & Biomolecular Chemistry Org. Biomol. Chem. |
| Direitos |
aberto |
| Fonte |
PubMed |
| Tipo |
Artigo de periódico |
