One-dimensional porous La_0.5Sr_0.5CoO_2.91 nanotubes as a highly efficient electrocatalyst for rechargeable lithium-oxygen batteries

<p>The electrochemical performance of one-dimensional porous La_0.5Sr_0.5CoO_2.91 nanotubes as a cathode catalyst for rechargeable nonaqueous lithium-oxygen (Li-O₂) batteries is reported here for the first time. In this study, one-dimensional porous La_0.5Sr_0.5CoO_2.91 nanotubes were prepared by a simple and efficient electrospinning technique. These materials displayed an initial discharge capacity of 7205 mAh g^-1 with a plateau at around 2.66 V at a current density of 100 mA g^-1. It was found that the La_0.5Sr_0.5CoO_2.91 nanotubes promoted both oxygen reduction and oxygen evolution reactions in alkaline media and a nonaqueous electrolyte, thereby improving the energy and coulombic efficiency of the Li-O₂ batteries. The cyclability was maintained for 85 cycles without any sharp decay under a limited discharge depth of 1000 mAh g^-1, suggesting that such a bifunctional electrocatalyst is a promising candidate for the oxygen electrode in Li-O₂ batteries.</p>