Thermochromism and switchable paramagnetism of cobalt(ii) in thiocyanate ionic liquids


Autoria(s): Osborne, Stephen J; Wellens, Sil; Ward, Chris; Felton, Solveig; Bowman, Robert M; Binnemans, Koen; Swadzba-Kwasny, Malgorzata; Gunaratne, H Q Nimal; Nockemann, Peter
Data(s)

2015

Resumo

<p>Temperature-dependent switching of paramagnetism of a cobalt(ii) complex is observed in an ionic liquid solution. Paramagnetic and thermochromic switching occur simultaneously due to a reversible change in coordination. This reversible switching is possible in the ionic liquid solution, which enables mobility of thiocyanate anions by remaining mobile at low temperatures and acts as an anion reservoir.</p>

Formato

application/pdf

Identificador

http://pure.qub.ac.uk/portal/en/publications/thermochromism-and-switchable-paramagnetism-of-cobaltii-in-thiocyanate-ionic-liquids(7973cea4-ab68-496b-85b8-c75b9905777c).html

http://dx.doi.org/10.1039/C5DT01829C

http://pure.qub.ac.uk/ws/files/17483433/Thermochromism_and_switchable_paramagnetism_of_cobalt_II_in_thiocyanate_ionic_liquids.pdf

Idioma(s)

eng

Direitos

info:eu-repo/semantics/openAccess

Fonte

Osborne , S J , Wellens , S , Ward , C , Felton , S , Bowman , R M , Binnemans , K , Swadzba-Kwasny , M , Gunaratne , H Q N & Nockemann , P 2015 , ' Thermochromism and switchable paramagnetism of cobalt(ii) in thiocyanate ionic liquids ' Dalton Transactions , vol 44 , no. 25 , pp. 11286-11289 . DOI: 10.1039/C5DT01829C

Tipo

article