BACTERIAL OXIDATION OF BENZOCYCLOALKENES TO YIELD MONOL, DIOL AND TRIOL METABOLITES


Autoria(s): BOYD, DR; SHARMA, ND; STEVENSON, PJ; CHIMA, J; GRAY, DJ; DALTON, H; Stevenson, Paul
Data(s)

29/07/1991

Resumo

<p>Benzylic monooxygenation of benzocycloalkenes, 2-4, by enzymes in intact cultures of Pseudomonas putida UV4 yielded exclusively the [R] enantiomers, 6-8, and the derived ketones 10-12; by contrast, biotransformation of benzocyclobutene, 1, yielded both monooxygenation (5 and 9), dioxygenation (13, 14 and 15), and trioxygenation (16) products.</p>

Identificador

http://pure.qub.ac.uk/portal/en/publications/bacterial-oxidation-of-benzocycloalkenes-to-yield-monol-diol-and-triol-metabolites(4f6da9d9-c4a5-41c8-a255-96fa7bf9125d).html

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

BOYD , D R , SHARMA , N D , STEVENSON , P J , CHIMA , J , GRAY , D J , DALTON , H & Stevenson , P 1991 , ' BACTERIAL OXIDATION OF BENZOCYCLOALKENES TO YIELD MONOL, DIOL AND TRIOL METABOLITES ' Tetrahedron Letters , vol 32 , no. 31 , pp. 3887-3890 .

Palavras-Chave #BACTERIAL OXIDATION #PSEUDOMONAS-PUTIDA UV4 #BENZOCYCLOALKENES #ALCOHOL AND KETONE METABOLITES #PSEUDOMONAS-PUTIDA #NAPHTHALENE #TOLUENE
Tipo

article