Palladium-Catalyzed Oxidative Synthesis of Highly Functionalized Ortholactones
| Data(s) |
18/05/2015
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| Resumo |
A palladium-catalyzed oxidative reaction is reported which converts dihydropyrans to their corresponding ortholactone. The products are formed in good to excellent yields with a very high level of chemoselectivity and functional group tolerance. Mechanistic studies confirm that the reaction proceeds by a Wacker-type mechanism. |
| Identificador | |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Baddeley , K L , Cao , Q , Muldoon , M J & Cook , M J 2015 , ' Palladium-Catalyzed Oxidative Synthesis of Highly Functionalized Ortholactones ' Chemistry - A European Journal , vol 21 , no. 21 , pp. 7726-7730 . DOI: 10.1002/chem.201500862 |
| Tipo |
article |
