Silicon-Directed Rhenium-Catalyzed Allylic Substitutions with N‑Hydroxycarbamates, N‑Hydroxysulfonamides, and Hydroxamic Acids

Autoria(s): Chavhan, Sanjay W.; McAdam, Catherine A.; Cook, Matthew J.
Data(s)

2014
Resumo

A rhenium-catalyzed N-selective allylic amination reaction of N-hydroxycarbamates has been developed. This reaction occurs with excellent N/O selectivity and with complete carbon selectivity on the allylic system. The reaction is tolerant of many functional groups and also proceeds with N-hydroxysulfonamides and hydroxamic acids.
Identificador

http://pure.qub.ac.uk/portal/en/publications/silicondirected-rheniumcatalyzed-allylic-substitutions-with-nhydroxycarbamates-nhydroxysulfonamides-and-hydroxamic-acids(40f00811-71b0-4f5c-83b8-179d46f0b94c).html

http://dx.doi.org/10.1021/jo501992p
Idioma(s)

eng
Direitos

info:eu-repo/semantics/restrictedAccess
Fonte

Chavhan , S W , McAdam , C A & Cook , M J 2014 , ' Silicon-Directed Rhenium-Catalyzed Allylic Substitutions with N‑Hydroxycarbamates, N‑Hydroxysulfonamides, and Hydroxamic Acids ' Journal of Organic Chemistry , vol 79 , no. 22 , pp. 11234−11240 . DOI: 10.1021/jo501992p
Tipo

article
Acesso ao item digital