Selective formation of a polar incomplete coordination cage induced by remote ligand substituents
Data(s) |
2012
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Resumo |
Instead of highly symmetrical T-symmetry cages common in self-assembly, the p-NMe2-substituted triphosphine CH3C{CH2P(4-C6H4NMe2)(3) gives open, polar C-3 symmetry cages [Ag-6(triphos)(4)X-3](3+) which lack one of the expected face-capping anions; despite its subtlety this difference occurs selectively in solution and two examples have been crystallographically characterised.<br/> |
Identificador | |
Idioma(s) |
eng |
Direitos |
info:eu-repo/semantics/restrictedAccess |
Fonte |
James , S , Giri , N , Clegg , W , Harrington , R , Horton , P & Hursthouse , M 2012 , ' Selective formation of a polar incomplete coordination cage induced by remote ligand substituents ' Chemical Communications , vol 48 , pp. 4061-4063 . |
Tipo |
article |