Highly diastereoselective hydrosilylations of allylic alcohols
| Data(s) |
04/04/2014
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| Resumo |
The highly syn-selective hydrosilylation of allylic alcohols was developed which, following oxidation, provided 1,3 alcohols containing two contiguous stereocentres. Through judicious choice of silane the complementary anti-selective hydrosilylation was also developed. This protocol was applied to the synthesis of an all syn polyketide stereotriad. © 2014 The Royal Society of Chemistry. |
| Identificador |
http://dx.doi.org/10.1039/c4cc00138a http://www.scopus.com/inward/record.url?eid=2-s2.0-84895745261&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
McLaughlin , M G & Cook , M J 2014 , ' Highly diastereoselective hydrosilylations of allylic alcohols ' Chemical Communications , vol 50 , no. 26 , pp. 3501-3504 . DOI: 10.1039/c4cc00138a |
| Tipo |
article |
