Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate
Data(s) |
01/02/2007
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Resumo |
<p>The title compound, [Ni2Cl2(C9H10NO2)(2)]center dot CH3OH, is a dinuclear unit built up by two nickel(II) complexes, bridged by two Cl atoms. The coordination geometry around each Ni-II atom can be considered as distorted square-pyramidal, with the tridendate chelate Schiff base ligands coordinating in a trans conformation through their imine N atom and phenoxy and alkoxy O atoms.</p> |
Identificador | |
Idioma(s) |
eng |
Direitos |
info:eu-repo/semantics/restrictedAccess |
Fonte |
Van Hecke , K , Nockemann , P , Binnemans , K & Van Meervelt , L 2007 , ' Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate ' Acta Crystallographica Section E: Structure Reports Online , vol 63 , pp. M569-M571 . DOI: 10.1107/S1600536807002292 |
Palavras-Chave | #SCHIFF-BASE LIGANDS #CRYSTALLINE-STRUCTURE #STRUCTURAL DIVERSITY #MOLECULAR-STRUCTURE #MAGNETIC-PROPERTIES #SPIN CLUSTERS #COMPLEXES #TETRANUCLEAR #TRINUCLEAR #REACTIVITY |
Tipo |
article |