Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate


Autoria(s): Van Hecke, Kristof; Nockemann, Peter; Binnemans, Koen; Van Meervelt, Luc
Data(s)

01/02/2007

Resumo

<p>The title compound, [Ni2Cl2(C9H10NO2)(2)]center dot CH3OH, is a dinuclear unit built up by two nickel(II) complexes, bridged by two Cl atoms. The coordination geometry around each Ni-II atom can be considered as distorted square-pyramidal, with the tridendate chelate Schiff base ligands coordinating in a trans conformation through their imine N atom and phenoxy and alkoxy O atoms.</p>

Identificador

http://pure.qub.ac.uk/portal/en/publications/dimuchlorobis22hydroxyethyliminomethylphenolatokappa-n3oo--nickelii-methanol-solvate(0a9da68b-2eb6-4919-93be-2712a21284a2).html

http://dx.doi.org/10.1107/S1600536807002292

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Van Hecke , K , Nockemann , P , Binnemans , K & Van Meervelt , L 2007 , ' Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate ' Acta Crystallographica Section E: Structure Reports Online , vol 63 , pp. M569-M571 . DOI: 10.1107/S1600536807002292

Palavras-Chave #SCHIFF-BASE LIGANDS #CRYSTALLINE-STRUCTURE #STRUCTURAL DIVERSITY #MOLECULAR-STRUCTURE #MAGNETIC-PROPERTIES #SPIN CLUSTERS #COMPLEXES #TETRANUCLEAR #TRINUCLEAR #REACTIVITY
Tipo

article