Nanoscale mapping of oxygen vacancy kinetics in nanocrystalline Samarium doped ceria thin films


Autoria(s): Doria, S.; Yang, N.; Kumar, A.; Jesse, S.; Tebano, A.; Aruta, C.; Di Bartolomeo, E.; Arruda, T.M.; Kalinin, S.V.; Licoccia, S.; Balestrino, G.
Data(s)

2013

Resumo

The position-dependent oxygen vacancy dynamics induced by a biased scanning probe microscopy tip in Samarium doped ceria thin films grown on MgO (100) substrates is investigated. The granularity of the samples gives rise to spatially dependent local electrochemical activity, as explored by electrochemical strain microscopy. The kinetics of the oxygen vacancy relaxation process is investigated separately for grain boundaries and grains. Higher oxygen vacancy concentration variation and slower diffusion are observed in the grain boundary regions as compared to the grains.

Identificador

http://pure.qub.ac.uk/portal/en/publications/nanoscale-mapping-of-oxygen-vacancy-kinetics-in-nanocrystalline-samarium-doped-ceria-thin-films(6d10ae54-4587-46e3-9801-ff467994ed55).html

http://dx.doi.org/10.1063/1.4826685

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Doria , S , Yang , N , Kumar , A , Jesse , S , Tebano , A , Aruta , C , Di Bartolomeo , E , Arruda , T M , Kalinin , S V , Licoccia , S & Balestrino , G 2013 , ' Nanoscale mapping of oxygen vacancy kinetics in nanocrystalline Samarium doped ceria thin films ' Applied Physics Letters , vol 103 , 171605 , pp. 1-4 . DOI: 10.1063/1.4826685

Tipo

article