Probing chemistry and kinetics of reactions in heterogeneous catalysts


Autoria(s): Youngs, Tristan G. A.; Manyar, Haresh; Bowron, Daniel T.; Gladden, Lynn F.; Hardacre, Christopher
Data(s)

01/09/2013

Resumo

Using benzene hydrogenation over Pt/SiO2 as an industrially-relevant example, we show that state-of-the-art neutron total scattering methods spanning a wide Q-range now permit relevant time-resolved catalytic chemistry to be probed directly in situ within the pore of the catalyst. The method gives access to the reaction rates on both nanometric and atomic length scales, whilst simultaneously providing an atomistic structural viewpoint on the reaction mechanism itself.

Formato

application/pdf

Identificador

http://pure.qub.ac.uk/portal/en/publications/probing-chemistry-and-kinetics-of-reactions-in-heterogeneous-catalysts(783dd9c2-8212-4f28-b959-8adbcf144ac4).html

http://dx.doi.org/10.1039/C3SC51477C

http://pure.qub.ac.uk/ws/files/5171564/Probing_chemistry_and_kinetics_of_reactions_in_heterogeneous_catalysts.pdf

Idioma(s)

eng

Direitos

info:eu-repo/semantics/openAccess

Fonte

Youngs , T G A , Manyar , H , Bowron , D T , Gladden , L F & Hardacre , C 2013 , ' Probing chemistry and kinetics of reactions in heterogeneous catalysts ' Chemical Science , vol 4 , no. 9 , pp. 3484-3489 . DOI: 10.1039/C3SC51477C

Palavras-Chave #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all)
Tipo

article