Alkylated organic cages: from porous crystals to neat liquids
| Data(s) |
2012
|
|---|---|
| Resumo |
<p>Rigid organic iminospherand cages are rendered meltable by multiple alkylation; below their melting points they can take the form of permanently porous crystals, crystals unstable to desolvation or nonporous glassy solids depending on chain length and branching; melting points as low as 50 degrees C are observed and a fully Newtonian liquid phase is obtained above 80 degrees C. Thin glassy fibres can be drawn out from a molten phase.</p> |
| Identificador | |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Giri , N , Davidson , C E , Melaugh , G , Del Popolo , M G , Jones , J T A , Hasell , T , Cooper , A I , Horton , P N , Hursthouse , M B & James , S L 2012 , ' Alkylated organic cages: from porous crystals to neat liquids ' Chemical Science , vol 3 , no. 6 , pp. 2153-2157 . DOI: 10.1039/c2sc01007k |
| Palavras-Chave | #MOLECULAR-CRYSTALS #SOLIDS #POROSITY #NITROGEN #ADSORPTION |
| Tipo |
article |
