A dramatic shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction on palladium catalysts
Data(s) |
1997
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Resumo |
<p>Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O-2 at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction.</p> |
Identificador | |
Idioma(s) |
eng |
Direitos |
info:eu-repo/semantics/restrictedAccess |
Fonte |
Fitzsimons , G , Hardacre , C , Patterson , W R , Rooney , J J , Clarke , J K A , Smith , M R & Ormerod , R M 1997 , ' A dramatic shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction on palladium catalysts ' Catalysis Letters , vol 45 , no. 3-4 , pp. 187-191 . |
Palavras-Chave | #X-RAY-ABSORPTION #SUPPORT #SPECTROSCOPY #falling initial distributions of deuterio-isomers #DEUTERIUM #Pd catalysts #novel supports and pretreatments #cyclopentane/D-2 exchange #EXAFS #PARTICLE-SIZE #SITES |
Tipo |
article |