A computational study of the mechanism of CO oxidation by a ceria supported surface rhodium oxide layer


Autoria(s): Song, Weiyu; Jansen, Antonius P J; Degirmenci, Volkan; Ligthart, D A J Michel; Hensen, Emiel J M
Data(s)

10/05/2013

Resumo

A mechanism of CO oxidation by a thin surface oxide of Rh supported on ceria is proposed: CO is oxidized by the Rh-oxide film, which is subsequently reoxidized by a ceria surface O atom. The proposed mechanism is supported by in situ Raman spectroscopic investigations.

Identificador

http://pure.qub.ac.uk/portal/en/publications/a-computational-study-of-the-mechanism-of-co-oxidation-by-a-ceria-supported-surface-rhodium-oxide-layer(911b2cb1-f6f4-44cd-bbe6-371a667eb543).html

http://dx.doi.org/10.1039/c3cc40670a

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Song , W , Jansen , A P J , Degirmenci , V , Ligthart , D A J M & Hensen , E J M 2013 , ' A computational study of the mechanism of CO oxidation by a ceria supported surface rhodium oxide layer ' Chemical Communications , vol 49 , no. 37 , pp. 3851-3 . DOI: 10.1039/c3cc40670a

Palavras-Chave #/dk/atira/pure/subjectarea/asjc/2500/2506 #Metals and Alloys #/dk/atira/pure/subjectarea/asjc/2500/2505 #Materials Chemistry #/dk/atira/pure/subjectarea/asjc/2500/2508 #Surfaces, Coatings and Films #/dk/atira/pure/subjectarea/asjc/2500/2504 #Electronic, Optical and Magnetic Materials #/dk/atira/pure/subjectarea/asjc/2500/2503 #Ceramics and Composites #/dk/atira/pure/subjectarea/asjc/1500/1503 #Catalysis #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all)
Tipo

article