Electrochemical synthesis of Mo2C catalytical coatings for the water-gas shift reaction
| Data(s) |
01/10/2007
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| Resumo |
The electroreduction of CO32- ions on a molybdenum cathode in a NaCl-KCl-Li2CO3 melt was studied by cyclic voltarnmetry. The electrochemical synthesis of Mo2C on molybdenum substrates has been performed at It 23 K for 7 h with a cathodic current density of 5 mA cm(-2). If molybdenum carbide is present as a thin (ca. 500 nm) film on a molybdenum substrate (Mo2C/Mo), its catalytic activity in the water gas-shift reaction is enhanced by at least an order of magnitude compared to that of the bulk Mo2C phase. |
| Identificador | |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Kuznetsov , S A , Dubrovskiy , A R , Rebrov , E & Schouten , J C 2007 , ' Electrochemical synthesis of Mo2C catalytical coatings for the water-gas shift reaction ' ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES , vol 62 , no. 10-11 , pp. 647-654 . |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600/1606 #Physical and Theoretical Chemistry |
| Tipo |
article |
