Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts


Autoria(s): Dubrovskii, A.R.; Kuznetsov, S.A.; Rebrov, Evgeny; Schouten, J.C.
Data(s)

01/07/2008

Resumo

Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO42 and CO32- are catalytically more active than bulk Mo2C or the commercial catalyst Cu-ZnO-Al2O3 by one and three orders of magnitude, respectively.

Identificador

http://pure.qub.ac.uk/portal/en/publications/catalytic-mo2c-coatings-for-the-water-gas-shift-reaction-electrosynthesis-in-molten-salts(52ecd9be-f019-4427-ac81-10cc1f4792f5).html

http://dx.doi.org/10.1134/S0023158408040216

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Dubrovskii , A R , Kuznetsov , S A , Rebrov , E & Schouten , J C 2008 , ' Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts ' Kinetics and Catalysis , vol 49 , no. 4 , pp. 594-598 . DOI: 10.1134/S0023158408040216

Palavras-Chave #/dk/atira/pure/subjectarea/asjc/1500/1503 #Catalysis #/dk/atira/pure/subjectarea/asjc/1600/1606 #Physical and Theoretical Chemistry
Tipo

article