Formation of nickel-thiolate aggregates via reaction with CH2Cl2


Autoria(s): Wang, Q.; Marr, Andrew; Blake, A.J.; Wilson, C.; Schroder, M.
Data(s)

2003

Resumo

Reaction of the mononuclear nickel-thiolate complex [Ni(L-1)(dppe)] with CH2Cl2 affords the novel pentanuclear complex Ni5Cl2(L-1)(4)(dppe)(2)], while [Ni(L-1)(dcpe)] reacts with CH2Cl2 to give the binuclear species [Ni2Cl2(L-2)(dcpe)(2)] in which two L-1 units are linked by a methylene group derived from CH2Cl2.

Identificador

http://pure.qub.ac.uk/portal/en/publications/formation-of-nickelthiolate-aggregates-via-reaction-with-ch2cl2(c85ac13b-ed2f-4e3a-a3e0-7bf1b0de9c9e).html

http://dx.doi.org/10.1039/b309523a

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Wang , Q , Marr , A , Blake , A J , Wilson , C & Schroder , M 2003 , ' Formation of nickel-thiolate aggregates via reaction with CH2Cl2 ' Chemical Communications , vol 2003 , pp. 2776-2777 . DOI: 10.1039/b309523a

Tipo

article