OBSERVATION OF BIPHASIC KINETICS IN LIGHT-INDUCED SPIN-STATE CROSSOVER IN AN IRON(II) COMPLEX IN SOLUTION


Autoria(s): Alobaidi, A.H.R.; Mcgarvey, J.J.; Taylor, Katie; Bell, Steven; Jensen, K.B.; Toftlund, H.
Data(s)

1993

Resumo

Relaxation of the 1A1 half arrow right over half arrow left 5T2 spin equilibrium in acetonitrile of the complex of Fe(II) with the multidentate pyridyl macrocyclic ligand N,N',N''-tris(2-pyridylmethyl)-1,4,7-triazacyclodecane (tp[10]aneN3) after perturbation by a pulsed laser provides the first example of biphasic kinetics for spin crossover in solution with a fast (tau

Identificador

http://pure.qub.ac.uk/portal/en/publications/observation-of-biphasic-kinetics-in-lightinduced-spinstate-crossover-in-an-ironii-complex-in-solution(34b81960-e80f-44f1-a2ff-f0f7194f7cb8).html

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Alobaidi , A H R , Mcgarvey , J J , Taylor , K , Bell , S , Jensen , K B & Toftlund , H 1993 , ' OBSERVATION OF BIPHASIC KINETICS IN LIGHT-INDUCED SPIN-STATE CROSSOVER IN AN IRON(II) COMPLEX IN SOLUTION ' Chemical Communications , vol 1 , pp. 536-538 .

Tipo

article