Anion-templated formation of a unique inorganic 'super-adamantoid' cage [Ag-6(triphos)(4)(O3SCF3)(4)](2+) [triphos = (PPh2CH2)(3)CMe]

Autoria(s): James, Stuart; Mingos, D.M.P.; White, A.J.P.; Williams, D.J.
Data(s)

1998
Resumo

In the presence of templating anions, 2:3 molar mixtures of triphos and silver(I) cations unexpectedly give novel hexanuclear cages, which result from an unusual 'endo-methyl' geometry of the triphos ligands.
Identificador

http://pure.qub.ac.uk/portal/en/publications/aniontemplated-formation-of-a-unique-inorganic-superadamantoid-cage-ag6triphos4o3scf342-triphos--pph2ch23cme(ae71ba3e-d342-4d91-9788-bb2178c20c69).html
Idioma(s)

eng
Direitos

info:eu-repo/semantics/restrictedAccess
Fonte

James , S , Mingos , D M P , White , A J P & Williams , D J 1998 , ' Anion-templated formation of a unique inorganic 'super-adamantoid' cage [Ag-6(triphos)(4)(O3SCF3)(4)](2+) [triphos = (PPh2CH2)(3)CMe] ' Chemical Communications , vol 1998 , pp. 2323-2324 .
Tipo

article
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