Effect of weak hydrogen bonding and included solvent on the crystal structure of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2


Autoria(s): Suman, P.; Dyer, P.W.; Dyson, P.J.; James, Stuart; Steed, J.W.
Data(s)

1998

Resumo

Crystallisation of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2 from dichloromethane-diethyl ether (1:1) affords two different solvates; trans-Pt{PPh2(C16H15)}(2)Cl-2. CH2Cl2 1 and trans-Pt{PPh2(C16H15)}(2)Cl-2. Et2O 2; the CH2Cl2 forms H-bonding interactions with the complex whereas the Et2O participates only in weak van der Waals interactions; these differences arise from the different hydrogen-bonding characteristics of each solvent.

Identificador

http://pure.qub.ac.uk/portal/en/publications/effect-of-weak-hydrogen-bonding-and-included-solvent-on-the-crystal-structure-of-the-squareplanar-complex-transptpph2c16h152cl2(5cf7cec6-6433-4989-b6bc-6e42aa0b327f).html

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Suman , P , Dyer , P W , Dyson , P J , James , S & Steed , J W 1998 , ' Effect of weak hydrogen bonding and included solvent on the crystal structure of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2 ' New Journal of Chemistry , vol 22 , pp. 1311-1313 .

Tipo

article