Imitating micelles as a way to control coordination self-assembly: cage-polymer switching directed rationally by solvent polarity or pH
| Data(s) |
07/02/2011
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| Resumo |
Disguising a metal complex as a micelle by using amphiphilic phosphine ligands enables it to switch between a coordination polymer and a discrete cage in response to solvent polarity or pH; this medium-dependent behaviour of the complex is rational because it parallels that of true micelles. |
| Identificador | |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Giri , N & James , S 2011 , ' Imitating micelles as a way to control coordination self-assembly: cage-polymer switching directed rationally by solvent polarity or pH ' Chemical Communications , vol 47 , no. 5 , pp. 1458-1460 . DOI: 10.1039/c0cc04196c |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1500/1503 #Catalysis #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all) #/dk/atira/pure/subjectarea/asjc/2500/2503 #Ceramics and Composites #/dk/atira/pure/subjectarea/asjc/2500/2504 #Electronic, Optical and Magnetic Materials #/dk/atira/pure/subjectarea/asjc/2500/2505 #Materials Chemistry #/dk/atira/pure/subjectarea/asjc/2500/2506 #Metals and Alloys #/dk/atira/pure/subjectarea/asjc/2500/2508 #Surfaces, Coatings and Films |
| Tipo |
article |
