Green photochemistry: photo-Friedel-Crafts acylations of 1,4-naphthoquinone in room temperature ionic liquids
Data(s) |
2009
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Resumo |
The photo-Friedel-Crafts acylation of 1,4-naphthoquinone with various aldehydes was investigated in a series of room temperature ionic liquids. High conversions and selectivities were achieved in [C(2)mim](+)-based ionic liquids with the highest isolated yields found in [C(2)mim][NTf2]. The developed procedure allowed for a replacement of hazardous solvents such as benzene and acetonitrile which are commonly used for this transformation. |
Identificador |
http://dx.doi.org/10.1039/b913252j http://www.scopus.com/inward/record.url?scp=70449364044&partnerID=8YFLogxK |
Idioma(s) |
eng |
Direitos |
info:eu-repo/semantics/restrictedAccess |
Fonte |
Murphy , B , Goodrich , P , Hardacre , C & Oelgemoller , M 2009 , ' Green photochemistry: photo-Friedel-Crafts acylations of 1,4-naphthoquinone in room temperature ionic liquids ' Green Chemistry , vol 11 , no. 11 , pp. 1867-1870 . DOI: 10.1039/b913252j |
Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/2300/2304 #Environmental Chemistry #/dk/atira/pure/subjectarea/asjc/2300/2310 #Pollution |
Tipo |
article |