Asymmetric rhodium carbenoid insertion into the Si-H bond.
| Data(s) |
1996
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| Resumo |
Buck, Richard T.; Doyle, Michael P.; Drysdale, Martin J.; Ferris, Leigh; Forbes, David C.; Haigh, David; Moody, Christopher J.; Pearson, Neil D.; Zhou, Qi-Lin. Dep. Chemistry, Loughborough Univ., Loughborough, Leicestershire, UK. Tetrahedron Letters (1996), 37(42), 7631-7634. Publisher: Elsevier, CODEN: TELEAY ISSN: 0040-4039. Journal written in English. CAN 125:328854 AN 1996:644681 CAPLUS (Copyright (C) 2009 ACS on SciFinder (R)) Abstract Decompn. of Me 2-diazophenylacetate in the presence of dimethylphenylsilane and a chiral dirhodium(II) catalyst results in Si-H insertion of the intermediate carbenoid to give PhCH(SiMe2Ph)CO2Me with varying degrees of enantioselectivity (up to 47% ee; 47% using (S)-Rh2L4, LH = I). |
| Identificador | |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Buck , R T , Doyle , M P , Drysdale , M J , Ferris , L , Forbes , D C , Haigh , D , Moody , C J , Pearson , N D & Zhou , Q-L 1996 , ' Asymmetric rhodium carbenoid insertion into the Si-H bond. ' Tetrahedron Letters , vol 37 , pp. 7631-7634 . |
| Tipo |
article |
