Remote chiral induction in the organocatalytic hydrosilylation of aromatic ketones and ketimines
| Data(s) |
20/02/2006
|
|---|---|
| Resumo |
Lewis basic, metal-free pyridyloxazolines catalyze the redn. of prochiral arom. ketones and ketimines with Cl3SiH in good enantioselectivity (? 94% ee). Arene-arene interactions between the substrate and the catalyst are likely to play a role in the enantiodifferentiation process. |
| Identificador |
http://dx.doi.org/10.1002/anie.200503941 http://www.scopus.com/inward/record.url?scp=33745661731&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Malkov , A V , Liddon , A J P S , Ramirez-Lopez , P , Bendova , L , Haigh , D & Kocovsky , P 2006 , ' Remote chiral induction in the organocatalytic hydrosilylation of aromatic ketones and ketimines ' Angewandte Chemie International Edition , vol 45 , no. 9 , pp. 1432-1435 . DOI: 10.1002/anie.200503941 |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all) |
| Tipo |
article |
