Speciation of Chlorometallate Ionic Liquids Based on Gallium(III) and Indium(III)
| Data(s) |
2010
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|---|---|
| Resumo |
A range of ionic liquids was prepared by mixing 1-alkyl-3-methylimidazolium chloride with gallium(III) chloride or indium(III) chloride in various ratios, producing both acidic and basic compositions. Their speciation was investigated using Ga-71 NMR or In-115 NMR spectroscopy, as well as extended X-ray absorption fine structure. Polynuclear Lewis acidic anions, [MxCl3x+1](-), were found in chlorogallate(III) ionic liquids, but not in chloroindate(III) systems. |
| Identificador |
http://dx.doi.org/10.1071/CH10014 http://www.scopus.com/inward/record.url?scp=77953011412&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Hardacre , C , Murphy , R , Seddon , K , Srinivasan , G & Swadzba-Kwasny , M 2010 , ' Speciation of Chlorometallate Ionic Liquids Based on Gallium(III) and Indium(III) ' Australian Journal of Chemistry , vol 63 , no. 5 , pp. 845-848 . DOI: 10.1071/CH10014 |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all) |
| Tipo |
article |
