Chemoenzymatic synthesis of the carbasugars carba-beta-L-galactopyranose, carba-beta-L-talopyranose and carba-alpha-L-talopyranose from methyl benzoate


Autoria(s): Boyd, Derek; Sharma, Narain; Bowers, N.I.; Coen, G.B.; Malone, John; O'Dowd, Colin; Stevenson, Paul; Allen, Christopher
Data(s)

21/03/2010

Resumo

The cis-dihydrodiol metabolite from methyl benzoate has been used as a synthetic precursor of carba-beta-L-galactopyranose, carba-beta-L-talopyranose and carba-alpha-L-talopyranose. The structures and absolute configurations of these carbasugars were determined by a combination of NMR spectroscopy, stereochemical correlation and X-ray crystallography.

Identificador

http://pure.qub.ac.uk/portal/en/publications/chemoenzymatic-synthesis-of-the-carbasugars-carbabetalgalactopyranose-carbabetaltalopyranose-and-carbaalphaltalopyranose-from-methyl-benzoate(6c4fbc38-5ff2-4265-977a-0e4796fb7af5).html

http://dx.doi.org/10.1039/b921545j

http://www.scopus.com/inward/record.url?scp=77749344421&partnerID=8YFLogxK

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Boyd , D , Sharma , N , Bowers , N I , Coen , G B , Malone , J , O'Dowd , C , Stevenson , P & Allen , C 2010 , ' Chemoenzymatic synthesis of the carbasugars carba-beta-L-galactopyranose, carba-beta-L-talopyranose and carba-alpha-L-talopyranose from methyl benzoate ' Organic and Biomolecular Chemistry , vol 8 , no. 6 , pp. 1415-1423 . DOI: 10.1039/b921545j

Palavras-Chave #/dk/atira/pure/subjectarea/asjc/1600/1606 #Physical and Theoretical Chemistry #/dk/atira/pure/subjectarea/asjc/1600/1605 #Organic Chemistry #/dk/atira/pure/subjectarea/asjc/1300/1303 #Biochemistry
Tipo

article