[Ag(NH3)(2)]ClO4: Crystal structures, phase transition, and vibrational spectra
Data(s) |
2002
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Resumo |
[Ag(NH3)(2)](ClO4) is obtained from a solution of AgClO4 in cone. ammonia as colourless single crystals (orthorhombic, Pnmn, Z = 4, a = 795.2(1) pm, b 617.7(1) pm, c = 1298.2(2) pm, R-all = 0.0494). The structure consists of linearly coordinated cations, [Ag(NH3)(2)](+), stacked in a staggered conformation and of tetrahedral (ClO4)(-) anions. A first order phase transition was observed between 210 and 200 K and the crystal structure of the low-temperature modification (monoclinic. P2/m, Z = 4, a = 789.9(5) pm, b = 604.1(5) pm, c = 1290.4(5) pm, beta = 97.436(5)degrees, at 170 K, R-all = 0.0636) has also been solved. Spectroscopic investigations (IR/Raman) have been carried out and the assignment of the spectra is discussed. |
Identificador | |
Idioma(s) |
eng |
Direitos |
info:eu-repo/semantics/restrictedAccess |
Fonte |
Nockemann , P & Meyer , G 2002 , ' [Ag(NH3)(2)]ClO4: Crystal structures, phase transition, and vibrational spectra ' ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE , vol 628 , pp. 1636-1640 . |
Tipo |
article |