Two mercuric ammoniates: [Hg(NH3)(2)][HgCl3](2) and [Hg(NH3)(4)](ClO4)(2)


Autoria(s): Nockemann, Peter; Meyer, G.
Data(s)

2003

Resumo

[Hg(NH3)(2)][HgCl3](2) (1) is obtained by saturating an equimolar solution of HgCl2 and NH4Cl with Hg(NH2)Cl at 75 degreesC. 1 crystallizes in the orthorhombic space group Pmna with a = 591.9(1) pm, b = 800.3(1) pm, c = 1243.3(4) pm, Z = 2. The structure consists of linear cations [Hg(NH3)(2)](2+) and T-shaped anions [HgCl3](-). The coordination sphere of mercury is

Identificador

http://pure.qub.ac.uk/portal/en/publications/two-mercuric-ammoniates-hgnh32hgcl32-and-hgnh34clo42(a8d58e3c-9556-4be4-97e9-81cadf719154).html

http://www.scopus.com/inward/record.url?scp=0037259426&partnerID=8YFLogxK

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Nockemann , P & Meyer , G 2003 , ' Two mercuric ammoniates: [Hg(NH3)(2)][HgCl3](2) and [Hg(NH3)(4)](ClO4)(2) ' ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE , vol 629 , no. 1 , pp. 123-128 .

Palavras-Chave #/dk/atira/pure/subjectarea/asjc/1600/1604 #Inorganic Chemistry
Tipo

article