Two mercuric ammoniates: [Hg(NH3)(2)][HgCl3](2) and [Hg(NH3)(4)](ClO4)(2)
Data(s) |
2003
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Resumo |
[Hg(NH3)(2)][HgCl3](2) (1) is obtained by saturating an equimolar solution of HgCl2 and NH4Cl with Hg(NH2)Cl at 75 degreesC. 1 crystallizes in the orthorhombic space group Pmna with a = 591.9(1) pm, b = 800.3(1) pm, c = 1243.3(4) pm, Z = 2. The structure consists of linear cations [Hg(NH3)(2)](2+) and T-shaped anions [HgCl3](-). The coordination sphere of mercury is |
Identificador |
http://www.scopus.com/inward/record.url?scp=0037259426&partnerID=8YFLogxK |
Idioma(s) |
eng |
Direitos |
info:eu-repo/semantics/restrictedAccess |
Fonte |
Nockemann , P & Meyer , G 2003 , ' Two mercuric ammoniates: [Hg(NH3)(2)][HgCl3](2) and [Hg(NH3)(4)](ClO4)(2) ' ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE , vol 629 , no. 1 , pp. 123-128 . |
Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600/1604 #Inorganic Chemistry |
Tipo |
article |