Synthesis of isomeric polyacetylenes based on natural hydroxy matricaria esters
| Data(s) |
03/10/2009
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|---|---|
| Resumo |
The construction of a library of natural and related polyacetylenes using a convergent synthetic strategy based on a palladium mediated cross-coupling reaction is described. The systematic synthetic study led to all possible alkene isomers of the hydroxy matricaria esters 29-32, and the corresponding tiglates 1-4. The synthesis of many of these compounds is described for the first time. |
| Identificador |
http://dx.doi.org/10.1016/j.tet.2009.07.082 http://www.scopus.com/inward/record.url?scp=69249165001&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Garrais , S , Turkington , J & Goldring , W 2009 , ' Synthesis of isomeric polyacetylenes based on natural hydroxy matricaria esters ' Tetrahedron , vol 65 , no. 40 , pp. 8418-8427 . DOI: 10.1016/j.tet.2009.07.082 |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1300/1303 #Biochemistry #/dk/atira/pure/subjectarea/asjc/1600/1605 #Organic Chemistry #/dk/atira/pure/subjectarea/asjc/3000/3002 #Drug Discovery |
| Tipo |
article |
