Rapid annulation of tropolone units via a pyrylium ylide 1,3-dipolar cycloaddition reaction
| Data(s) |
06/01/2010
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|---|---|
| Resumo |
The tropolone subunit of the naturally occurring alkaloid rubrolone aglycon is synthesized via a short reaction sequence starting with a 1,3-dipolar cycloaddition of a pyrylium ylide and indenone, followed by enone oxidation, oxygen bridge elimination and finally hydroxy group oxidation. |
| Identificador |
http://dx.doi.org/10.1016/j.tetlet.2009.10.081 http://www.scopus.com/inward/record.url?scp=70649107883&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Tchabanenko , K , McIntyre , P & Malone , J 2010 , ' Rapid annulation of tropolone units via a pyrylium ylide 1,3-dipolar cycloaddition reaction ' Tetrahedron Letters , vol 51 , no. 1 , pp. 86-88 . DOI: 10.1016/j.tetlet.2009.10.081 |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1300/1303 #Biochemistry #/dk/atira/pure/subjectarea/asjc/1600/1605 #Organic Chemistry #/dk/atira/pure/subjectarea/asjc/3000/3002 #Drug Discovery |
| Tipo |
article |
