Azaarene cis-dihydrodiol-derived 2,2 '-bipyridine ligands for asymmetric allylic oxidation and cyclopropanation

Autoria(s): Boyd, Derek; Sharma, Narain; Sbircea, Lenuta; Murphy, Deirdre; Belhocine, Tayeb; Malone, John; James, Stuart; Allen, Christopher; Hamilton, John
Data(s)

2008
Resumo

Biphenyl dioxygenase-catalysed cis-dihydroxylation of 2-chloroquinoline, 2-chloro-3-methylquinoline and 2-chloro-6-phenylpyridine substrates yielded the corresponding enantiopure cis-dihydrodiols; enantiopure 2,2'-bipyridines, synthesised in four steps from 2-chloroquinoline, proved to be efficient chiral ligands in catalytic asymmetric allylic oxidation and cyclopropanation reactions of alkenes.
Identificador

http://pure.qub.ac.uk/portal/en/publications/azaarene-cisdihydrodiolderived-22-bipyridine-ligands-for-asymmetric-allylic-oxidation-and-cyclopropanation(07a720a8-77d8-4d76-aa7b-32e36ce3b657).html

http://dx.doi.org/10.1039/b814678k

http://www.scopus.com/inward/record.url?scp=55849140950&partnerID=8YFLogxK
Idioma(s)

eng
Direitos

info:eu-repo/semantics/restrictedAccess
Fonte

Boyd , D , Sharma , N , Sbircea , L , Murphy , D , Belhocine , T , Malone , J , James , S , Allen , C & Hamilton , J 2008 , ' Azaarene cis-dihydrodiol-derived 2,2 '-bipyridine ligands for asymmetric allylic oxidation and cyclopropanation ' Chemical Communications , vol null , no. 43 , pp. 5535-5537 . DOI: 10.1039/b814678k
Palavras-Chave #/dk/atira/pure/subjectarea/asjc/2500/2506 #Metals and Alloys #/dk/atira/pure/subjectarea/asjc/2500/2505 #Materials Chemistry #/dk/atira/pure/subjectarea/asjc/2500/2508 #Surfaces, Coatings and Films #/dk/atira/pure/subjectarea/asjc/2500/2504 #Electronic, Optical and Magnetic Materials #/dk/atira/pure/subjectarea/asjc/2500/2503 #Ceramics and Composites #/dk/atira/pure/subjectarea/asjc/1500/1503 #Catalysis #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all)
Tipo

article
Acesso ao item digital