Mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2)
Data(s) |
01/04/2008
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Resumo |
Single crystals of mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2), were obtained from aqueous solutions of 1,2,4-triazole and Hg(NO3)(2)center dot 2H(2)O. The crystal structure [monoclinic, P2(1)/c (no. 14), a = 499.6(2), b = 1051.2(4), c = 711.1(3) pm, beta = 117.55(1)degrees, Z = 2, R, for 890 reflections with I-0 > 2 sigma(I-0): 0.0369] contains linear centrosymmetric Hg(Imf)(2) molecules with Hg-N distances of only 203.5(7)pm. Two plus two intra- and intermolecular nitrogen atoms add to an effective coordination number of 6. |
Identificador |
http://dx.doi.org/10.1002/zaac.200700507 http://www.scopus.com/inward/record.url?scp=53849125780&partnerID=8YFLogxK |
Idioma(s) |
eng |
Direitos |
info:eu-repo/semantics/restrictedAccess |
Fonte |
Nockemann , P , Pantenburg , I & Meyer , G 2008 , ' Mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2) ' ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE , vol 634 , no. 4 , pp. 613-615 . DOI: 10.1002/zaac.200700507 |
Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600/1604 #Inorganic Chemistry |
Tipo |
article |