Highly efficient asymmetric hetero-Diels-Alder reactions of carbonyl compounds catalyzed by Lewis acid platinum complexes of conformationally flexible NUPHOS-type diphosphines
| Data(s) |
20/12/2004
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| Resumo |
Conformationally flexible NUPHOS-type diphosphines have been resolved as their diastereopure platinum BINOLate complexes delta- and lambda-[(NUPHOS)Pt{(S)-BINOL}] and the corresponding enantiopure Lewis acids delta- and lambda-[(NUPHOS)Pt(OTf)(2)], being generated by protonation with trifluoromethanesulfonic acid, act as highly efficient catalysts for the hetero-Diels-Alder reaction of nonactivated conjugated dienes with aryl glyoxals and glyoxylate esters, giving ee's as high as 99%. |
| Identificador |
http://dx.doi.org/10.1021/om04392z http://www.scopus.com/inward/record.url?scp=11044226706&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Doherty , S , Knight , J G , Hardacre , C , Lou , H K , Newman , C R , Rath , R , Campbell , S & Nieuwenhuyzen , M 2004 , ' Highly efficient asymmetric hetero-Diels-Alder reactions of carbonyl compounds catalyzed by Lewis acid platinum complexes of conformationally flexible NUPHOS-type diphosphines ' Organometallics , vol 23 , no. 26 , pp. 6127-6133 . DOI: 10.1021/om04392z |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600/1604 #Inorganic Chemistry #/dk/atira/pure/subjectarea/asjc/1600/1605 #Organic Chemistry |
| Tipo |
article |
