Liquid and solid-state structures of 1,3-dimethylimidazolium salts


Autoria(s): Bowron, D.T.; Hardacre, Christopher; Holbrey, John; McMath, S.E.J.; Nieuwenhuyzen, Mark; Soper, A.K.
Data(s)

2003

Resumo

Using neutron and single crystal X-ray diffraction the structures of 1,3-dimethylimidazolim chloride and hexafluorophosphate salts have been determined in the liquid and the solid-state. The relative hydrogen bonding characteristics and sizes of the two anions force the ions to pack differently. In each case, a strong correlation between the crystal structure and liquid structure is found.

Identificador

http://pure.qub.ac.uk/portal/en/publications/liquid-and-solidstate-structures-of-13dimethylimidazolium-salts(8e564795-1081-46d4-83cf-7cbb1b853302).html

http://www.scopus.com/inward/record.url?scp=30744453199&partnerID=8YFLogxK

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Bowron , D T , Hardacre , C , Holbrey , J , McMath , S E J , Nieuwenhuyzen , M & Soper , A K 2003 , ' Liquid and solid-state structures of 1,3-dimethylimidazolium salts ' IONIC LIQUIDS AS GREEN SOLVENTS: PROGRESS AND PROSPECTS , vol 856 , pp. 151-161 .

Tipo

article