Alternating copolymerisation of styrene and carbon monoxide in ionic liquids


Autoria(s): Hardacre, Christopher; Holbrey, John; Katdare, Suhas; Seddon, Kenneth
Data(s)

01/03/2002

Resumo

Room temperature ionic liquids have been used as solvents for the palladium-catalysed copolymerisation of styrene and carbon monoxide. The behaviour of various ionic liquids, the nature and concentration of palladium catalyst, and the reusability of the catalyst-ionic liquid system are discussed. The effects of cation, anion and alkyl chain length of the ionic liquids on the reaction are also addressed. The yield of the polyketone in the ionic liquid systems is enhanced over conventional solvents studied under similar conditions.

Identificador

http://pure.qub.ac.uk/portal/en/publications/alternating-copolymerisation-of-styrene-and-carbon-monoxide-in-ionic-liquids(6ac9aba3-df7b-48db-9b91-cf001b5ee079).html

http://dx.doi.org/10.1039/b111157b

http://www.scopus.com/inward/record.url?scp=57249109797&partnerID=8YFLogxK

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Hardacre , C , Holbrey , J , Katdare , S & Seddon , K 2002 , ' Alternating copolymerisation of styrene and carbon monoxide in ionic liquids ' Green Chemistry , vol 4 , no. 2 , pp. 143-146 . DOI: 10.1039/b111157b

Palavras-Chave #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all)
Tipo

article