Liquid clathrate formation in ionic liquid-aromatic mixtures


Autoria(s): Holbrey, John; Reichert, W.M.; Nieuwenhuyzen, Mark; Sheppard, O.; Hardacre, Christopher; Rogers, R.D.
Data(s)

21/02/2003

Resumo

1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate-benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2: 1 inclusion compound.

Identificador

http://pure.qub.ac.uk/portal/en/publications/liquid-clathrate-formation-in-ionic-liquidaromatic-mixtures(e453a5f1-da41-4c46-8cf2-32dc849fbd12).html

http://dx.doi.org/10.1039/b212726a

http://www.scopus.com/inward/record.url?scp=0037459012&partnerID=8YFLogxK

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Holbrey , J , Reichert , W M , Nieuwenhuyzen , M , Sheppard , O , Hardacre , C & Rogers , R D 2003 , ' Liquid clathrate formation in ionic liquid-aromatic mixtures ' Chemical Communications , vol * , no. 4 , pp. 476-477 . DOI: 10.1039/b212726a

Palavras-Chave #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all)
Tipo

article