Marked enantioselectivity enhancements for Diels-Alder reactions in ionic liquids catalysed by platinum diphosphine complexes
| Data(s) |
01/12/2004
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|---|---|
| Resumo |
Asymmetric Diels-Alder reactions using platinum complexes of BINAP, or of conformationally flexible NUPHOS-type diphosphines, have been compared in dichloromethane and selected ionic liquids. Significant enhancements in the enantioselectivity (Deltaee approximate to 20%), as well as reaction rate, were achieved in ionic liquids compared with the organic media. |
| Identificador |
http://dx.doi.org/10.1039/b312761c http://www.scopus.com/inward/record.url?scp=1442326799&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Doherty , S , Goodrich , P , Hardacre , C , Luo , H-K , Rooney , D , Seddon , K & Styring , P 2004 , ' Marked enantioselectivity enhancements for Diels-Alder reactions in ionic liquids catalysed by platinum diphosphine complexes ' Green Chemistry , vol 6 , no. 1 , pp. 63-67 . DOI: 10.1039/b312761c |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all) |
| Tipo |
article |
