Densities, speeds of sound, isentropic compressibilities, refractive indexes, and viscosities of tetrahydrofuran with haloalkane or alkyl ethanoate at T = 303.15 K


Autoria(s): Oswal, S.L.; Gardas, Ramesh; Phalak, R.P.
Data(s)

01/02/2005

Resumo

Isentropic compressibilities ?S, excess isentropic compressibilities image, excess molar volumes VE, viscosity deviations ??, and excess Gibbs energy of activation of viscous flow ?G*E for nine binary mixtures of C4H8O with CCl4, CHCl3, CHCl2CHCl2, 1-C6H13Cl, 1-C6H13Br, CH3CO2CH3, CH3CO2C2H5, CH3CO2C4H9, and CH3CO2C5H11 at 303.15 K have been derived from experimental densities ?, speeds of sound u, refractive indexes nD and viscosities ?. The limiting values of excess partial molar volumes of C4H8O at infinite dilution image in different solvents have been estimated. The results obtained for dynamic viscosity of binary mixtures were used to test the semi-empirical relations of Grunberg–Nissan, Tamura–Kurata, Hind–McLaughlin–Ubbelohde, Katti–Chaudhri, McAllister, Heric, and Auslaender. Finally, the experimental refractive indexes were compared with the predicted results for Lorentz–Lorenz, Dale–Gladstone, Eykman, Arago–Boit, Newton, Oster, Heller, and Wiener equations.

Identificador

http://pure.qub.ac.uk/portal/en/publications/densities-speeds-of-sound-isentropic-compressibilities-refractive-indexes-and-viscosities-of-tetrahydrofuran-with-haloalkane-or-alkyl-ethanoate-at-t--30315-k(84ca5148-5bce-4be4-8dcb-9676922f1938).html

http://dx.doi.org/10.1016/j.tca.2004.08.001

http://www.scopus.com/inward/record.url?scp=12344273327&partnerID=8YFLogxK

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Oswal , S L , Gardas , R & Phalak , R P 2005 , ' Densities, speeds of sound, isentropic compressibilities, refractive indexes, and viscosities of tetrahydrofuran with haloalkane or alkyl ethanoate at T = 303.15 K ' Thermochimica Acta , vol 426 (1-2) , no. 1-2 , pp. 199-206 . DOI: 10.1016/j.tca.2004.08.001

Palavras-Chave #/dk/atira/pure/subjectarea/asjc/1600/1601 #Chemistry (miscellaneous) #/dk/atira/pure/subjectarea/asjc/1600/1606 #Physical and Theoretical Chemistry
Tipo

article