Base free dynamic kinetic resolution of secondary alcohols using ‘piano stool’ complexes of N-heterocyclic carbenes
| Data(s) |
02/05/2007
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|---|---|
| Resumo |
Piano stool complexes of rhodium and iridium activated by fluorinated and non-fluorinated N-heterocyclic carbene (NHC) ligands were shown to be catalysts for racemization in the one-pot chemoenzymic dynamic kinetic resolution (DKR) of secondary alcohols. Excellent conversions and good enantioselectivities were observed for alkyl aryl and dialkyl secondary alcohols. |
| Identificador |
http://dx.doi.org/10.1021/om700462c http://www.scopus.com/inward/record.url?scp=34547377175&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Marr , A , Pollock , C L & Saunders , G 2007 , ' Base free dynamic kinetic resolution of secondary alcohols using ‘piano stool’ complexes of N-heterocyclic carbenes ' Organometallics , vol 26(14) , no. 14 , pp. 3283-3285 . DOI: 10.1021/om700462c |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600/1604 #Inorganic Chemistry #/dk/atira/pure/subjectarea/asjc/1600/1605 #Organic Chemistry |
| Tipo |
article |
