Tandem enzyme-catalysed oxidations of alkyl phenyl sulfides and alkyl benzenes: enantiocomplementary routes to chiral phenols.
| Data(s) |
2002
|
|---|---|
| Identificador |
http://dx.doi.org/10.1039/b205903g http://www.scopus.com/inward/record.url?scp=0036966847&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Boyd , D , Das Sharma , N , Ljubez , V , Byrne , B E , Shepherd , S , Allen , C , Kulakov , L , Larkin , M & Dalton , H 2002 , ' Tandem enzyme-catalysed oxidations of alkyl phenyl sulfides and alkyl benzenes: enantiocomplementary routes to chiral phenols. ' Chemical Communications , vol 17 , no. 17 , pp. 1914-1915 . DOI: 10.1039/b205903g |
| Tipo |
article |
| Resumo |
Dioxygenase-catalysed trioxygenation of alkyl phenyl sulfides and alkyl benzenes yields enantiopure cis-dihydrodiol sulfoxides and triols respectively; naphthalene cis-dihydrodiol dehydrogenase-catalysed aromatisation of these diastereoisomers gives enantiopure catechols of either configuration. |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600 #Chemistry(all) |
