Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.
| Data(s) |
14/03/2010
|
|---|---|
| Formato |
1712 - 1714 |
| Identificador |
http://www.ncbi.nlm.nih.gov/pubmed/20177625 Chem Commun (Camb), 2010, 46 (10), pp. 1712 - 1714 http://hdl.handle.net/10161/4122 1364-548X |
| Idioma(s) |
ENG en_US |
| Relação |
Chem Commun (Camb) 10.1039/b925859k Chemical Communications |
| Tipo |
Journal Article |
| Cobertura |
England |
| Resumo |
A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation of the E-diastereomer. |
| Palavras-Chave | #Alkadienes #Amination #Amines #Catalysis #Platinum #Stereoisomerism |
