Total synthesis of cyanolide A and confirmation of its absolute configuration.
| Data(s) |
18/06/2010
|
|---|---|
| Formato |
2880 - 2883 |
| Identificador |
http://www.ncbi.nlm.nih.gov/pubmed/20491466 Org Lett, 2010, 12 (12), pp. 2880 - 2883 http://hdl.handle.net/10161/4106 1523-7052 |
| Idioma(s) |
ENG en_US |
| Relação |
Org Lett 10.1021/ol101022z Organic letters |
| Tipo |
Journal Article |
| Cobertura |
United States |
| Resumo |
The tandem allylic oxidation/oxa-Michael reaction promoted by the gem-disubstituent effect and the 2-methyl-6-nitrobenzoic anhydride (MNBA)-mediated dimerization were explored for the efficient and facile synthesis of cyanolide A. |
| Palavras-Chave | #Anhydrides #Animals #Glycosylation #Macrolides #Molecular Structure #Nitrobenzoates #Oxidation-Reduction #Schistosoma |
